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Had that happen once to some of my jars. Isolated jars from others and let them sit to see what would happen. Once the white met the brown colonization stop completely. Took one jar outside to examine...(Not to sniff). When I opened the lid it was an incredible musty muzzie smell that you pick up without even getting close to jar. Sort of like when you leave wet clothes somewhere in a bag and forget about them. Must have been some kind of mildew contam.