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Valium is pretty much a tranquilizer, thats why it can be used to bring people down if their havin a hard time with the trip. If you take a little bit say an hour or so before the trip it will probably take the edge off when your coming up.
"What business is it of yours what I do, read, buy, see, say, think, who I fuck, what I take into my body - as long as I do not harm another human being on this planet?" - Bill Hicks
I can't speak for mushrooms, but as far as LSA, LSD, and mescaline go, it has no impact on visuals or trippy thoughts; but if your heart is beating out of your chest and you're freaking out, like belly said, it'll take the edge off.
I'm prescribed 6mg klonopin/day, equiv ~60mg valium, and my last trip (10 strip of fractals) I didn't even take or need them. I took one on the comedown to go to bed.. 18 hours later.