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Shotgun: Thumbs down. You'd be surprised how many people survive the attempt. You get the wrong angle and the blast is directed out through the face rather than up into the brain-pan.
Drano: This is another one that people occasionally survive (much to thier misfortune). Thumbs down.
Jumping off a Bridge: Depends on the bridge, I guess. If I were to choose this one, I'd go with a rope 'round my neck to make sure my neck breaks. (With any luck, the head would pop clean off to be found later by some vagrant taking a leak in the bushes by the river-side. Nice touch.)
But really, I think a .357 to the cranium is the best and surest method. In fact, I'd get right on this if I were you. Satan, your Dark Lord, commands it.