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What kind of mushroom? How fresh are they? Where will the chips be laid out?
This might work with some species, but generally you want to innoculate with vegetative mycelium ['spawn']. Keep in mind that an important success factor is the ratio of spawn to substrate. Weed fungi can take over a poorly innoculated pile rather easily depending on your particular environment. A couple of mushrooms might not be enough. Many variables, but I'd imagine that it is possible to have some success doing this.