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Offlinewebsite123
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2-BR-LSD ---> iso-LSD
    #19270660 - 12/13/13 12:59 PM (10 years, 1 month ago)

i was wondering...
if i take 2br-lsd from the pharmacy( alleging that i am alcoholic or that i have cluster headaches)
and mix with benzene, leading to bromobenzene and iso-lsd theoretically,
because benzene is less eletropositive than lsd...
do u think benzene would do the work??
i was thinking about acetic acid, maybe...


Edited by website123 (12/13/13 01:07 PM)


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OfflinemuirileD
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Re: 2-BR-LSD ---> iso-LSD [Re: website123]
    #19270796 - 12/13/13 01:37 PM (10 years, 1 month ago)

you're trying to replace an aromatic bromide with hydride.

I'd think protection of the carbonyl is needed. Although I'm not sure if the brominated sp2 carbon would be the next most reactive position.

bromination of benzene is not as straight forward as plucking it from 1 compound to the next due to the breaking of aromaticity in the ring during the transition state. Also that method lacks the delivery of a hydride to the position the bromine just left.

Eh good luck


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Offlinewebsite123
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Re: 2-BR-LSD ---> iso-LSD [Re: muirileD]
    #19309004 - 12/21/13 06:20 PM (10 years, 1 month ago)

Quote:

muirileD said:

bromination of benzene is not as straight forward as plucking it from 1 compound to the next due to the breaking of aromaticity in the ring during the transition state. Also that method lacks the delivery of a hydride to the position the bromine just left.




no, ur totally right i see, thats why i think i could mix pure acetic acid with benzene and then add a mixture of water and 2-BR-LSD that whay the hydide would not be a problem because of the water and then the BR would be free(i'd imagine by pouring it on the top right of the becker very slowly and let it in the dark for 4 days and check with bluelight eventually) , besides, the first to change in an organic is the radical...
what do u think??


Edited by website123 (12/21/13 08:03 PM)


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OfflinepsilocybinjunkieM
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Re: 2-BR-LSD ---> iso-LSD [Re: website123]
    #19309567 - 12/21/13 06:20 PM (10 years, 1 month ago)

This thread has been closed.

Reason:
Wrong forum for this kind of discussion.


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