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 Coaster
Baʿal
 
Registered: 05/22/06
Posts: 33,501
Loc: Deep in the Valley
Last seen: 12 years, 6 months
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i only buy from the clinix when its not harvest tyme
im only allowed 6 plants and that doesnt support my habit 
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hawksapprentice
Yearns to Snowboard
Registered: 06/06/03
Posts: 3,195
Loc: Oregon
Last seen: 10 months, 22 days
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 Re: FUCKING MONOPOLIES  [Re: Coaster]
#10187794 - 04/17/09 11:47 PM (15 years, 2 days ago) |
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Then you don't know how to grow. You should be able to get 3 pounds every 3 months if you do it properly and have the right strain. And dude, if you go through that much weed you might want to slow down.
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"I celebrate the Earth, my home, my mother, my grave, and as long as men are Man they must, if they would preserve the integrated being, do the same---[and preserve]--this rank casual hungry smelly sweaty lusting transitory body, my oozy pulpy liquid-bag-swollen body, bones, blood, hair glands, my bejeweled sex; I love and celebrate it all. never to let men forget that they are animals as much as gods---that is one thing I shall say."
Edward Abbey
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Coaster
Baʿal
Registered: 05/22/06
Posts: 33,501
Loc: Deep in the Valley
Last seen: 12 years, 6 months
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slow down?
i dont understand what you are trying to say
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DragonChaser
Ice in Her Ass and Pussy
Registered: 04/27/06
Posts: 7,212
Last seen: 6 years, 5 months
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Re: FUCKING MONOPOLIES [Re: Coaster]
#10190656 - 04/18/09 03:16 PM (15 years, 2 days ago) |
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Quote:
Coaster said:
o ya well look what i synthesized
You didn't synthesize anything. You had a bottle of liquid K and put some vanilla extract in it, it onto a plate or something and heated it until the liquid evaporated and you had crystals left over.
I once extracted fentanyl from patches and laced basil with it, that doesn't mean I "synthesized" fentanyl.
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My name is Mud
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Coaster
Baʿal
Registered: 05/22/06
Posts: 33,501
Loc: Deep in the Valley
Last seen: 12 years, 6 months
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no way man i synthed it its so ez a gorilla can do it
Step 1: (o-chlorophenyl)-cyclopentyl ketone
119.0 g of cyclopentyl bromide and 19.4 g of magnesium are reacted in ether or THF to give a cyclopentyl Grignard reagent. The best yields are obtained if the ether solvent is distilled from the Grignard under vacuum and replaced with hydrocarbon solvent, such as benzene. 55.2 g of o-chlorobenzonitrile is then added to the reaction mixture and stirred for three days. The reaction is then hydrolyzed by pouring it onto a mixture of crushed ice and ammonium chloride, containing some ammonium hydroxide. Extracion of the mixture with organic solvent gives o-chlorophenylcyclopentylketone, bp 96-97 C (0.3 mm Hg) (CAS# 6740-85-8).
Step 2: alpha-bromo (o-chlorophenyl)-cyclopentyl ketone
To 21.0 g of the above ketone is added 10.0 g of bromine in 80 ml of carbon tetrachloride dropwise at 0 deg. C. After all of the Br2 has been added, an orange suspension forms. This is washed with a dilute aqueous solution of sodium bisulfite and evaporated to give 1-bromocyclopentyl-(o-chlorophenyl)-ketone, bp 111-114 C (0.1 mm Hg). Yield is ~66%. This bromoketone is unstable and must be used immediately. Also attempts to distill it at 0.1 mm Hg lead to some decomposition, so it should be used without further purification.
The bromination may also be carried out with N-bromosuccinimide in somewhat higher yields (~77%).
Step 3: 1-hydroxycyclopentyl-(o-chlorophenyl)-ketone-N-methylimine
29.0g of above bromoketone is dissolved in 50 ml of liquid methylamine freebase. Benzene may also be used as solvent. After one hour, the excess liquid methylamine is allowed to evaporate, although increasing the reaction time to 4-5 days may increase yield. The residue is then dissolved in pentane and filtered. The solvent is evaporated to yield 1-hydroxy-cyclopentyl-(o-chlorophenyl)-ketone N-methylimine, mp 62 C (yield ~84%).
Step 4: 2-Methylamino-2-(o-chlorophenyl)-cyclohexanone (Ketamine)
The final step is a thermal rearrangement, and gives almost quantitative yield after 180 C for 30 min. An alternative to the use of decalin as solvent in this step is to use a pressure bomb.
2.0 g of the preceeding N-methylimine is dissolved in 15 ml of decalin and refluxed for 2.5 h. After evaporation of the solvent under reduced pressure, the residue is extracted with dilute hydrochloric acid, the solution treated with decolorizing charcoal, and the resulting acidic solution is made basic. The liberated product, 2-methylamino-2-(o-chlorophenyl)-cyclohexanone (Ketamine), after recrystallization from pentane-ether, has a mp of 92-93C. The hydrochloride has a mp of 262-263 C.
As with PCE, the freebase is too caustic to be smoked, and must be converted into the HCl salt in order to be consumed in this manner.
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